Fred, Is there any remedy. I have been calling this insoluble
salt staining, or chloride staining (although I never lived in a place with
snow, we do see it from irrigation water high in nitrates, or mortar alkaline
salts wicking, particularly in granite). Is there a cure once the salts have crystallized?
From: fhueston@gmail.com
[mailto:fhueston@gmail.com] On Behalf Of Dr Fred
Sent: Monday, June 29, 2009 10:38 PM
To: Restoration and Maintenance
Subject: RE: [sccpartners] deicer !
Roger,
yes there are deicers that will not damage stone, here is
some info on the types
Are your Ice and Snow Melters
Destroying your Stone and Terrazzo Floors
The Deterioration of Stone & Masonry through the Crystallization of Deicing
Salts
Frederick M. Hueston
The crystallization of deicing salts found in many snow and ice melter can cause
severe deterioration of stone, terrazzo and masonry surfaces. This
crystallization is called subflorescence. Snow and Ice Melters containing
Calcium Chloride, etc are the cause for this damage. .Problems associated with
subflorescence can be diagnosed and identified by visual clues, such as
spalling and pitting. Accurate diagnosis of subflorescence can be confirmed
with laboratory testing. Preventative applications might include application of
chemical injection and coating the masonry with a sealer or impregnator as well
as switching to a snow and ice melter that contain non-crystalline salts. The
following article will explore the problems caused by these deicers and what
can be done to prevent damage to your stone, terrazzo or masonry floors.
How do Deicer Cause Damage
The deposit of salts in the pores of stone and masonry is the major cause for
deterioration of these surfaces. These salts are contained in many popular snow
and ice melters. Boyer(1986) contributes deicing salts
When snow and ice melts the salts used in deicers become soluble. The water
wicks into the pores of the stone and masonry carrying the salts with it. When
the water evaporates the salts recrystallize. The pressure created in the pores
of the stone and masonry cause the surface to flake off or spall. This process
is known as subflorescence.
4
Diagnosing and Identifying Subflorescence
An experience stone consultant can recognize the signs and symptoms of damage
caused by deicing salts. The stone and masonry will appear pitted(spalled).
This damage is observed in the walking path at the entrances of the building.
The damage tends to lessen the further away from the entrance. Certain stones
such as some limestone’s and slates will flake off in sheets. Terrazzo and
marble will become pitted.
Core samples can also be taken and sent to a lab for testing and verification
if necessary.
Snow and Ice Melters
There are many brands of snow melters on the market. Many of these melters
contain salts that will crystallize and cause damage to stone and masonry. The
following are the salts you should avoid.
Rock Salt- Rock salt will go by the name of Halite but chemically it is simply
Sodium Chloride(NaCl). This is the most common salt sold for deicing and it is
also the least expensive and hence is the most widely used. It is also the salt
that causes the most damage to stone, terrazzo and masonry flooring.
Calcium and Magnesium Chloride(CaCl2 –MgCl2)- these are salts that come from
natural salt deposits in the Great Salt Lake in Utah. They are also destructive
to stone, terrazzo and masonry. They also can deposit a film on the surface of
the floor causing it to be slippery.
Potassium Chloride(KCL)- This salt is not a very good deicer by itself and is
often found mixed with other ingredients. It is often sold as a safer salt for
plants. But not for stone, terrazzo or masonry.
Ammonium Sulphate(NH4]2SO4 Stay far away from this salt. It is very damaging to
stone, terrazzo and masonry. It’s not used that much in deicers but if you see
it listed on the ingredients, don’t buy it.
Urea- Urea is commonly found in fertilizers. In its pure form it is less
damaging the most other salts. Most deicers containing Urea are not pure and
can be damaging to stone, terrazzo and masonry.
The above salts are in a sold crystalline form. There are liquid deicers
available containing Ethylene Glycol and Potassium acetate but liquids are
usually impractical to apply in schools and other public buildings.
Safe Deicers
Which salts are safe for stone, terrazzo and masonry flooring? Thanks to our
many icy roads a salt known as Calcium Magnesium acetate was developed. Not
only is this type of deicer more environmentally friendly it is also
biodegradable, non corrosive and less damaging to stone, terrazzo and masonry
surfaces. The down side you might guess is the expense. But what will that new
floor cost?
Safe for Concrete Deicers
The biggest concern with deicers is the corrosion of rebar in concrete. For
this reason many deicers are claiming to be safe for concrete. This is true as
far as less corrosion. Your concern is not necessarily corrosion but salt
crystallization. Make sure to check the ingredient of these so called safer
deicers by requesting a Material Safety Data Sheet (MSDS) or consult with a
stone expert.
As I travel in areas where deicer are used I see thousands of schools,
government buildings as well as public building with damage to stone, terrazzo
and masonry flooring. If the damage is caught in time a restoration company may
be able to repair the damage. If these harmful salts continue to be used you’ll
be replacing the
On Sun, Jun 28, 2009 at 11:27 PM, Roger Konarski <qm144@yahoo.com> wrote:
All,
Is there a
product that can be used to melt ice but not damage limestone flooring?
Currently the building is using a deicer that is pitting the stone. Thanks,
Roger
Konarski |
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Frederick M. Hueston PhD
www.stoneforensics.com
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